Q:
The initial free energy of the compact before sintering must be _______
Answer & Explanation
Answer: B) Negative
Explanation: Initially, the free energy of the system (compact) (dE) must be negative, that is, the free energy of solid-solid interfaces must have lower free energy than the solid-vapor interface. Thus, during sintering, the newly formed solid-solid interfaces (i.e. grain boundaries) replace the existing solid-vapor interfaces, thereby lowering the free energy of the system.
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